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CHLORIDE CHEMICALS

Chloride chemicals are a broad category of compounds containing chlorine (Cl⁻) that play vital roles in industries such as water treatment, pharmaceuticals, plastics, and metallurgy.







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INORGANIC CHLORIDES

1, Sodium Chloride (NaCl) – Common Salt

 Production: Mined from salt deposits (rock salt) or obtained via seawater evaporation.

 Applications: Food seasoning, water softening, chlorine production (via electrolysis).

2, Hydrogen Chloride (HCl)

 Production: Direct synthesis: Byproduct of chlorination reactions (e.g., PVC production).

 Applications: Production of vinyl chloride (PVC) and hydrochloric acid.

3, Calcium Chloride (CaCl₂)

 Production: Byproduct of the Solvay process (soda ash production).

 Applications: De-icing roads, desiccant, food preservative, concrete accelerator.

4,  Aluminum Chloride (AlCl₃)

 Production: Reaction of aluminum with chlorine gas.

 Applications: Friedel-Crafts catalyst (alkylation, acylation), water treatment.

5, Ferric Chloride (FeCl₃)

 Production: Chlorination of iron or as a byproduct of steel pickling.

 Applications: Wastewater treatment (coagulant), PCB etching, dye manufacturing.

ORGANIC CHLORIDES

1, Vinyl Chloride (C₂H₃Cl) – PVC Precursor

Production: Ethylene dichloride (EDC) cracking:

Applications: Polyvinyl chloride (PVC) for pipes, cables, flooring.

2,  Methylene Chloride (CH₂Cl₂) – Dichloromethane (DCM)

Production: Chlorination of methane.

Applications: Paint stripper, solvent in pharmaceuticals, aerosol propellant.

3, Chloroform (CHCl₃) – Trichloromethane

Production: Further chlorination of methane or DCM.

Applications: Solvent, anesthetic (historical use), refrigerant production.

4, Carbon Tetrachloride (CCl₄)

Production: Excess chlorination of methane.

Applications: Banned in many uses (ozone-depleting), formerly used in fire extinguishers.

5, Benzyl Chloride (C₇H₇Cl)

Production: Chlorination of toluene.

Applications: Production of benzyl alcohol, quaternary ammonium compounds (disinfectants).

6, Ethylene Dichloride (EDC, C₂H₄Cl₂)

Production: Direct chlorination or oxychlorination of ethylene.

Applications: Intermediate for vinyl chloride (PVC) production.



TYPICAL PROCESS

Chlorination is a key chemical process used to introduce chlorine atoms into organic and inorganic compounds.

Comparison of Chlorination MethodsE

CHLORIDE CHEMICALS
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SPECIALTY CHLORIDES

1,  Titanium Tetrachloride (TiCl₄)

- Production:  

  - Chlorination of titanium dioxide (TiO₂).  

 - Applications:  

  - Production of titanium metal (Kroll process), TiO₂ pigments.  


2, Silicon Tetrachloride (SiCl₄)

- Production:  

  - Chlorination of silicon or silica.  

- Applications:  

  - Semiconductor industry, silicone polymers.  


 3, Phosphorus Trichloride (PCl₃) & Pentachloride (PCl₅)

- Production:  

  - Chlorination of white phosphorus.  

- Applications:  

  - Agrochemicals (pesticides), flame retardants, pharmaceuticals.  


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