
INORGANIC CHLORIDES
1, Sodium Chloride (NaCl) – Common Salt
Production: Mined from salt deposits (rock salt) or obtained via seawater evaporation.
Applications: Food seasoning, water softening, chlorine production (via electrolysis).
2, Hydrogen Chloride (HCl)
Production: Direct synthesis: Byproduct of chlorination reactions (e.g., PVC production).
Applications: Production of vinyl chloride (PVC) and hydrochloric acid.
3, Calcium Chloride (CaCl₂)
Production: Byproduct of the Solvay process (soda ash production).
Applications: De-icing roads, desiccant, food preservative, concrete accelerator.
4, Aluminum Chloride (AlCl₃)
Production: Reaction of aluminum with chlorine gas.
Applications: Friedel-Crafts catalyst (alkylation, acylation), water treatment.
5, Ferric Chloride (FeCl₃)
Production: Chlorination of iron or as a byproduct of steel pickling.
Applications: Wastewater treatment (coagulant), PCB etching, dye manufacturing.
ORGANIC CHLORIDES
1, Vinyl Chloride (C₂H₃Cl) – PVC Precursor
Production: Ethylene dichloride (EDC) cracking:
Applications: Polyvinyl chloride (PVC) for pipes, cables, flooring.
2, Methylene Chloride (CH₂Cl₂) – Dichloromethane (DCM)
Production: Chlorination of methane.
Applications: Paint stripper, solvent in pharmaceuticals, aerosol propellant.
3, Chloroform (CHCl₃) – Trichloromethane
Production: Further chlorination of methane or DCM.
Applications: Solvent, anesthetic (historical use), refrigerant production.
4, Carbon Tetrachloride (CCl₄)
Production: Excess chlorination of methane.
Applications: Banned in many uses (ozone-depleting), formerly used in fire extinguishers.
5, Benzyl Chloride (C₇H₇Cl)
Production: Chlorination of toluene.
Applications: Production of benzyl alcohol, quaternary ammonium compounds (disinfectants).
6, Ethylene Dichloride (EDC, C₂H₄Cl₂)
Production: Direct chlorination or oxychlorination of ethylene.
Applications: Intermediate for vinyl chloride (PVC) production.
TYPICAL PROCESS
Chlorination is a key chemical process used to introduce chlorine atoms into organic and inorganic compounds.
Comparison of Chlorination MethodsE
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SPECIALTY CHLORIDES
1, Titanium Tetrachloride (TiCl₄)
- Production:
- Chlorination of titanium dioxide (TiO₂).
- Applications:
- Production of titanium metal (Kroll process), TiO₂ pigments.
2, Silicon Tetrachloride (SiCl₄)
- Production:
- Chlorination of silicon or silica.
- Applications:
- Semiconductor industry, silicone polymers.
3, Phosphorus Trichloride (PCl₃) & Pentachloride (PCl₅)
- Production:
- Chlorination of white phosphorus.
- Applications:
- Agrochemicals (pesticides), flame retardants, pharmaceuticals.
EQUIPMENT SUPPLY
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